- Increase in number of proton --> effective nuclear charge: increase
- Screening effect of inner shell electron --> : decrease
- Extra stability(write out ground state)
- Electron to electron repulsion --> : decrease
同 + 異 + 比較-->outweighing effect
Example: O and N
Oxygen and nitrogen has the same number of electron shell(同), although oxygen has 1 more number of proton than nitrogen(異), the electronic configurations of N and O are [He]2s2 2p3 and [He]2s2 2p4 respectively, where first electron of N being remove is in completely filled 2p3 orbital which give extra-stability . (異)
On the other hand, the first electron of O being removed is in a paired orbital, the electron to electron repulsion will lower its ionization enthalpy.(異)
The extra-stability and electron to electron repulsion together outweigh the effect in increase in proton number.(比較--> outweighing effect) Therefore the ionizationentalpy of N is higher than O
沒有留言:
張貼留言